The thermal maturity of sedimentary basins as revealed by magnetic mineralogy

The thermal evolution of sedimentary basins is usually constrained by maturity data, which is interpreted from Rock-Eval pyrolysis and vitrinite reflectance analytical results on field or boreholes samples. However, some thermal evolution models may be inaccurate due to the use of elevated maturities measured in samples collected within an undetected metamorphic contact aureole surrounding a magmatic intrusion. In this context, we investigate the maturity and magnetic mineralogy of 16 claystone samples from Disko-Svartenhuk Basin, part of the SE Baffin Bay volcanic margin. Samples were collected within thermal contact metamorphic aureoles near magma intrusions, as well as equivalent reference samples not affected by intrusions. Rock-Eval pyrolysis (T_max), and vitrinite reflectance (Ro) analysis were performed to assess the thermal maturity, which lies in the oil window when 435°C ≤ T_max ≤ 470°C and 0.6%–0.7% ≤ Ro ≤ 1.3%. In addition, we performed low- (<300K) and high-temperature (>300K) investigations of isothermal remanent magnetization to assess the magnetic mineralogy of the selected samples. The maturity results (0.37% ≤ Ro ≤ 2%, 22°C ≤ T_max ≤ 604°C) show a predominance of immature to early mature Type III organic matter, but do not reliably identify the contact aureole when compared to the reference samples. The magnetic assemblage of the immature samples consists of iron sulphide (greigite), goethite and oxidized or non-stoichiometric magnetite. The magnetic assemblage of the early mature to mature samples consists of stoichiometric magnetite and fine-grained pyrrhotite (<1 μm). These results document the disappearance of the iron sulphide (greigite) and increase in content of magnetite during normal burial. On the other hand, magnetite is interpreted to be the dominant magnetic mineral inside the contact aureole surrounding dyke/sill intrusions where palaeotemperatures indicate mature to over-mature state. Interestingly, the iron sulphide (greigite) is still detected in the contact aureole where palaeotemperatures exceeded 130°C. Therefore, the magnetic mineralogy is a sensitive method that can characterize normal burial history, as well as identify hidden metamorphic contact aureoles where the iron sulphide greigite is present at temperatures beyond its stability field.     

云南哀牢山-红河剪切带新生代富碱侵入岩中榍石年代学和地球化学特征

榍石作为副矿物在哀牢山-红河剪切带新生代富碱侵入岩中广泛存在。原位获取榍石矿物内部微量元素、U-Pb年龄和Sm-Nd同位素的空间变化对获取矿物和岩石的成因演化信息具有重要意义。本文使用四级杆/多接收电感耦合等离子体质谱(Quadrupole/Multi-Collector Inductively Coupled Plasma Mass Spectrometry,Q/MC-ICP-MS)与激光剥蚀系统(Laser Ablation,LA)联用,对哀牢山-红河剪切带5个富碱侵入岩体(桃花岩体、宁蒗-永胜岩体、哈播岩体、铜厂岩体和十里村岩体)中榍石开展了微区原位微量元素、U-Pb年代学和Sm-Nd同位素研究。微量元素分析结果表明,三江富碱侵入岩中榍石为岩浆成因,亏损Rb、Ba、Pb、Sr等大离子亲石元素,富集Th、U、Nb、Ta、Zr、Hf等高场强元素。榍石的稀土配分图均表现为明显右倾,不具有或具有弱的Eu负异常。与云南北衙、马厂箐矽卡岩矿床中的热液榍石相比,本文榍石在稀土元素组成上,具有较高的稀土元素总量、较高的Th/U、LREE/HREE和Ce/Ce*比值,具有较低的Eu/Eu*、Nb/Ta、Zr/Hf比值。微区原位LA-Q-ICP-MS U-Pb定年结果表明,研究区富碱岩体中榍石结晶年龄在32.5～37.9Ma之间,代表了岩体形成时代,与三江地区哀牢山-红河剪切带及其附近新生代富碱岩浆活动高峰期(～35Ma)一致,属于青藏高原晚碰撞期岩浆作用的产物。榍石微区原位LA-MCICP-MS Sm-Nd同位素分析结果显示,榍石颗粒的Nd同位素组成均一,表明榍石结晶过程中寄主岩浆的Nd同位素组成没有发生明显变化。各个富碱岩体之间的榍石Nd同位素组成变化范围在-6.8～-2.1之间,与全岩的同位素特征一致,表明榍石的原位微区Sm-Nd同位素可以作为富碱侵入岩研究中有效的示踪手段之一。     

川西甲基卡矿床外围中酸性侵入岩LA-ICP-MS锆石U-Pb年龄及地球化学特征

在川西甲基卡矿床外围新发现了建巴村中酸性侵入岩体,为了探讨其形成时代、成岩构造背景及其成矿条件,开展了LA-ICP-MC锆石U-Pb年代学和地球化学特征研究。结果表明: 该岩体的结晶年龄为(211.8±1.0) Ma; 岩石属于钙碱性-高钾钙碱性准铝质中酸性侵入岩系列,具有I型花岗岩类的特征,其物质来源可能为壳源物质与幔源物质部分熔融。地球化学特征表明其形成于后碰撞环境,与此时期内川西地区的区域性岩浆活动相对应。建巴村岩体的构造位置及岩浆活动特征指示其可能不具备形成伟晶岩矿床的条件。     

新型珊瑚海水混凝土力学性能试验研究

为了解决全珊瑚海水混凝土(coral aggregate seawater concrete,简称CASC)的脆性问题,采用碱式硫酸镁水泥(basic magnesium sulfate cement,简称BMSC)为胶凝材料和剑麻纤维为增韧材料制备了一种新型全珊瑚海水混凝土(NCASC),系统测定了基本力学性能,并与普通硅酸盐水泥制备的CASC、碱式硫酸镁水泥砂石混凝土(basic magnesium sulfate cement concrete,简称BMSCC)、普通砂石混凝土(ordinary portland cement concrete,简称OPC)以及普通轻骨料混凝土(lightweight aggregate concrete,简称LAC)的力学性能进行对比。结果表明:立方体抗压强度(f_(cu),m)在15~35 MPa范围内的NCASC的轴心抗压强度(f_c,m)、劈裂抗拉强度(f_(sp),m)与f_(cu),m之间具有较显著的线性关系;对于f_(cu),m为15~35 MPa的混凝土,相同强度NCASC的f_c,m高于OPC、LAC及BMSCC,其f_c,m与f_(cu),m比值最大,大致在0.85~0.96之间,NCASC的f_(sp),m比OPC和LAC高,但比BMSCC低,且随着强度的提高,OPC与NCASC的f_(sp),m间的差距在增大,而LAC和BMSCC与NCASC的f_(sp),m间的差距在缩小;在强度等级C15~C55的范围中,NCASC和CASC的f_(sp),m、f_c,m与f_(cu),m之间的关系基本可以采用相同的线性回归方程来描述,利用这两个回归线性方程得到对应于标准强度等级的CASC和NCASC的f_(sp),m和f_c,m数据,为CASC力学性能研究与结构设计提供参考依据。     

In situ measurements of wind‐driven salt fluxes through constructed channels in a coastal wetland ecosystem

A suite of instruments was deployed in a coastal wetland ecosystem in the Albemarle estuarine system, North Carolina (USA), to characterize wind‐driven transport of saltwater through a constructed (man‐made) channel. Flow velocity, electrical conductivity, and stage were measured in a representative channel over a 2‐month period from May to July 2014, during which 4 wind tides were observed. Collected data show that thousands of metric tons of salt were advected through the channel into coastal wetlands during each event, which lasted up to 4 days. The results reveal that as much as 36% of advected salts accumulated in the wetlands, suggesting that the cumulative effects of these events on the health of coastal wetlands in the Albemarle system may be substantial due to the abundance of constructed channels and the frequency of wind‐driven tidal events. This study is the first to quantify wind‐driven salt fluxes through constructed channels in coastal wetland settings.     

南海风暴潮对风场和外围海水敏感性研究

为探索来自西北太平洋台风风暴潮与南海局地生成台风风暴潮不同,本研究在假设两种台风气象条件相同情况下,研究随台风而来外围海水所形成增水对南海沿岸的影响。以0814"黑格比"强台风风暴潮为基础,使用ROMS(regional ocean modeling system)模式进行数值模拟并通过设计对比试验方法进行研究,研究发现在台风登陆时引起的增水最大,最大增水出现在台风路径右侧,其中在沿岸区域,外围海水形成增水约占总增水10%,且大约3 h后出现增水回震现象。同时,设计对比试验,研究来自西北太平洋台风风暴潮对台风路径、台风强度、台风移动速度和流入角等气象条件敏感性,并获得与前人一致的结果。     

Data-based modelling approach for variable density flow and solute transport simulation in a coastal aquifer

Data-based models, namely artificial neural network (ANN), support vector machine (SVM), genetic programming (GP) and extreme learning machine (ELM), were developed to approximate three-dimensional, density-dependent flow and transport processes in a coastal aquifer. A simulation model, SEAWAT, was used to generate data required for the training and testing of the data-based models. Statistical analysis of the simulation results obtained by the four models show that the data-based models could simulate the complex salt water intrusion process successfully. The selected models were also compared based on their computational ability, and the results show that the ELM is the fastest technique, taking just 0.5 s to simulate the dataset; however, the SVM is the most accurate, with a Nash-Sutcliffe efficiency (NSE) ≥ 0.95 and correlation coefficient R ≥ 0.92 for all the wells. The root mean square error (RMSE) for the SVM is also significantly less, ranging from 12.28 to 77.61 mg/L.     

离子色谱法测定海水中氯离子和硫酸根离子

氯离子和硫酸根离子是海水中重要的无机阴离子，在研究海洋生态变化、海洋循环作用过程与海洋全球气候变化等领域具有重要的指示意义。其测定方法较多，但缺少相应的测试方法。本文对测定海水中Cl^-，SO₄^2-的离子色谱方法进行了优化，选用IonPacAS14碳酸盐选择性离子色谱柱，以3.5 mmol/L Na₂CO₃+1 mmol/L NaHCO₃为流动相，可消除海水样品中碳酸盐及其他阴离子的干扰。该方法对Cl^-检出限为0.29 mg/L，线性相关系数r²=0.999 2，对SO₄^2-检出限为0.42 mg/L，线性相关系数r²=0.997 9。样品的加标回收率在95%~102%，Cl^-和SO₄^2-的相对标准偏差分别为1.92%和4.18%。该方法简便、迅速、灵敏、准确度高，可满足批量海水样品中Cl^-与SO₄^2-的准确测试。     

State of seawater intrusion and its adaptive management countermeasures in Longkou City of China

Longkou City is a coastal area,and lacks water resources.The overexploitation of groundwater causes seawater intrusion.At present,seawater intrudes an area of 68 km2.With the decrease of groundwater extraction,the seawater intrusion area has generally declined.The paper expounds the development process of seawater intrusion as well as the corresponding prevention and control measures of using groundwater replenishment and groundwater throttling in Longkou City.In view of the seawater intrusion problem in Longkou City,some adaptive management countermeasures are put forward,which include:Adjusting industrial and agricultural structure,promoting economic and social development to match water resources;improving water usage structure,optimizing the utilization of water resources;advancing the construction of a water-saving society,using water resources efficiently;implementing inter-basin water transfer,using water resources rationally;developing and utilizing unconventional water sources,making full use of water resources;strengthening water infrastructure construction,increasing the development and utilization potential of water resources;carrying out ecological restoration,protecting water resources and ecological environment;improving the management informationalization level,strengthening the capabilities of groundwater monitoring and management;increasing publicity,improving public awareness of participation.     

海水海砂混凝土双K断裂参数的确定

采用尺寸为515 mm×100 mm×100 mm初始缝高比从0.1变化至0.8的三点弯曲梁试件,利用试验测得起裂荷载Pini、最大荷载Pmax及对应的裂缝口张开位移CMODc等参数,研究了缝高比a0/h对海水海砂混凝土双K断裂参数的影响。并以相同配合比的淡水河砂梁作为对照组,进一步研究了海砂海水混凝土双K断裂参数与普通混凝土之间的关系。结果发现海水海砂混凝土断裂参数在a0/h=0.25～0.7范围内时可以认为是一常数;海水海砂混凝土梁断裂参数比相同配合比情况下的淡水河砂梁大且对边界影响更加敏感。